HANDBOOK OF CONDUCTIVE
LITHOGRAPHIC FILMS
(published April 2000)
This handbook has been produced
for those in the electronics industry as a guide to the specifications
and performance of a novel manufacturing process for electronic
interconnect which uses the offset lithographic printing process.
Over four years research work at
Brunel University has demonstrated the feasibility of manufacturing
electrical circuit interconnect via the established printing technology
of offset lithography. It has been shown that offset-lithography can be
used as a process for manufacture of low specification electrical
interconnect, leading to reduced production time and raw material use
when compared to conventional thick film printing approaches. Several
industrial applications are at present being developed, and a case study
is described in Chapter 3.
The specifications of a novel, lithographically printable ink with a
cured electrical resistance sufficiently low to enable it to form
interconnect for complex electrical systems are given.
The suitability of the offset lithographic process for fabricating a
wide variety of products including switch pad membranes, antenna and
interconnect circuitry is discussed.
Offset Lithography
Alois Senefelder (1771 - 1834) is accredited with the discovery of
planographic printing, but it was not until 1904 that Ira Rubel began
transferring the ink from the image plate to the paper using a rubber
cylinder.
Lithography relies on the action of two wetting functions on the surface
of a smooth and un-embossed printing plate. The planographic image plate
is photochemically treated to repel water where the printed image is,
and attract it in the non image areas. This allows an oil-based ink to
adhere only to the image areas.
Contact with inking and damping rollers allows the printing plate to
attract both water and ink as required, thus forming the image to be
printed. However, the image is not deposited directly onto the substrate
material (e.g. paper), but is instead “offset” on to an intermediate
or “blanket cylinder” that has a yielding surface. The blanket
cylinder then presses the ink film onto the surface of the substrate,
which is now supported on a separate impression cylinder
Standard lithographic printing machines have the following
characteristics:
-
High Speed (Typically
3000-10000 Impressions/hour).
-
Good Dimensional Control &
Excellent Registration of Images.
-
Low Cost per Sheet (Low Ink
Volume/Substrate)
1.2 PRINTED FILM SPECIFICATIONS
Types of Circuit which may be
produced
Substrate Materials
A wide range of substrates, such as paper, card, polyester,
polyethylene, polysulphone, cellulose, and polyimide may be used. Best
results are achieved from smooth but moderately absorbent materials such
as synthetic and filled papers. Substrate thicknesses of 0.050 to 0.300
mm can be printed on most offset machines.
Sheet Resistance
Sheet resistivity of 100 mOhm per square attainable. Normalised sheet
resistivity (25 microns) of 20 mOhm per square attainable. Sheet
resistance is determined by choice of substrate and on press controls.
Electrical and physical characterisation of the printed films has
enabled production tolerances to be determined and susceptibility to
environmental attack and mechanical wear to be established. In brief the
findings are as follows:
Achievable resistance tolerances:
Variation in resistance was found to be preliminary dependent upon the
ink delivery mechanism of the press. For the 1982 model Heidelberg GTO46
used in this study the following tolerances were achieved:
± 2.5 % variation in resistance over print runs of several hundred
units;
± 2.5 % variation in resistance from the leading to trailing edge of a
sheet;
± 15 % variation in resistance across the width of a sheet on a
manually set press.
Resolution and Alignment
Preferred minimum:
80 - 100 µm track, 60 µm gap
Current process limits:
60 µm track, 40 µm gap
60 µm track width structures have been successfully printed but exhibit
higher sheet resistances (typically 500 mOhm per square).
Resolution limits are determined by press alignment characteristics,
which for the press used in this study were found to be:
~40µm in side-lay alignment;
~20µm in front-lay alignment;
The alignment errors of larger presses may exceed the 40 µm stated
above, resulting in a larger minimum feature size.
Component Attachment Process
The facilities and trials were provided and performed at Mitel Telecom,
Portskewett.
-
Screen print on conductive
adhesive
-
Auto pick and place components
-
Low temperature bake to cure
joints
-
Bond strengths 30 - 50 % that
of tin/lead solder
Surface Mount Adhesives
The following adhesives were trialed in this study:
-
Ablebond 967 - 1
-
Ablebond 8380
-
Ablebond 8175 A
-
RS 496 295
Ablebond 967 - 1 was considered most
appropriate.
Through Hole Connection
Through hole connection is achieved by screen-printing adhesive through
holes during component attach process. Alternative processes such as
laser ablation may be appropriate for specific applications.
Environmental Test Specifications
The facilities and tests were provided and performed by Nortel
Technology, Harlow, Essex. The test regimes used:
-
IEC-68-2-60: pt.2: Ke: 1995.
Flowing Mixed Gas Corrosion (Test Method 1)
-
IEC 68-2-67:pt.2: Cy: 1995.
Damp heat steady state accelerated test 85 °C - 85% Relative
Humidity.
-
IEC-68-2-20: Ca: 1969. - BS
2011:Pt.2.1: Ca: 1977. Damp Heat, Steady State, 40 °C - 93%
Relative Humidity.
None of the samples exhibited a rise
in sheet resistance greater than 10%. Most samples exhibited a reduced
sheet resistivity resultant from film curing over the duration of the
test.
Summary
All these figures are derived from a single model of press operated
under typical print shop conditions. As a consequence aspects of these
results, which are dependent upon press condition and characteristics,
do not represent generic limits of the process. The printed films have
also successfully withstood basic environmental test regimes, including
humidity, corrosive atmospheres, elevated temperatures, thermal shock
and mechanical wear.
1.3 "SUITABILITY OF
PROCESS" ASSESSMENT
The following is a checklist for
assessing the suitability of conductive lithographically printed films
as alternatives to other technologies.
The ‘Suitability of Process’ checklist facilitates an initial
consideration of the process for new applications. This table
illustrates clearly the suitability of the process to unpopulated, low
current applications such as antenna, membrane switches, tags and
sensors. The success of more complex demonstrator devices illustrates
the capacity of the process, and highlights the additional developments
and changes of perception necessary for the process to enter mainstream
manufacture.
The appropriateness of the process to a product can be judged from the
responses to the questions. An ‘ideal’ response to the first
question in each section indicates high suitability. The likelihood for
the CLF technology to offer significant savings in cost and time will be
increased if the majority of the responses match the ideal model. If
none of the answers for a section are ‘ideal’ there will be
fundamental problems in implementing CLF technology.
Section
|
Question
|
Ideal Answer
|
Electrical
Characteristics
|
Is sheet resistivity below
100mOhm per square necessary
|
No
|
Is a continuous current
flow in excess of 120mA/1 mm track width required? (exact
limits depend upon precise track design and thermal transfer)
|
No
|
Substrate material
|
Are standard printing
substrates acceptable (cellulose and synthetic papers, and
plastics)
|
Yes
|
Are "FR4",
"Melinex" or "Kapton" substrates
necessary? (these materials can be printed but are harder to
process and exhibit lower adhesion using the current ink
formulations)
|
No
|
If "FR4",
"Melinex" or "Kapton" substrates are
required is it necessary to attach components?
|
No
|
Substrate rigidity
|
Does it form a structural
role within the product?
|
No
|
Does it form a structural
role within the product?
|
No
|
If the circuitry is single
sided can it be adhered to a mechanical support
|
Yes
|
If the substrate forms part
of the mechanical integrity of the product and is double sided
can it be held in a frame?
|
Yes
|
Component attachment
|
Is component attachment a
requirement
|
No
|
Can components be printed?
|
Yes
|
Can conductive adhesives or
mechanical clips be used?
|
Yes
|
Can surface-mount
components be used instead of through hole components?
|
Yes
|
Production
|
Can components be localised
to a separate board (as in some keyboards)? (resulting in one
large cheap PTF board and one small cheap conventional board,
instead of one large conventional board)
|
Yes
|
Will the production
cost/speed be better than the existing process (dependent upon
length of run)?
|
Yes
|
Process resolution
|
Are additional post print
process (assembly, protection etc. if necessary) lower
cost/faster than required for the existing manufacturing
process
|
Yes
|
Environmental exposure
|
Are the required track
widths wider than 80 -100µm
|
Yes
|
Will the unprotected
circuitry be exposed to humid atmospheres?
|
No
|
Will the unprotected
circuitry be exposed to corrosive atmospheres?
|
No
|
Will any of the
environmental protection process available (lamination,
printed barrier layer, encapsulation, lacquer) offer
acceptable protection?
|
Yes
|
Preliminary "suitability of
process" checklist designed to assess circuit applications
|